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Home > Product > Material & Chemicals > Organic & Printed Electronics > Dichloro(2 2:6 2-terpyridine)-

Dichloro(2 2:6 2-terpyridine)- | CAS Number: 151120-25-1

Catalog Number
ACM151120251
Product Name
Dichloro(2 2:6 2-terpyridine)-
Structure
CAS Number
151120-25-1
IUPAC Name
dichloroplatinum;2,6-dipyridin-2-ylpyridine;dihydrate
Synonyms
DICHLORO(2 2:6 2-TERPYRIDINE)-
Molecular Weight
535.29
Exact Mass
534.01900
Molecular Formula
C15H11N3.Cl2Pt.2H2O
Purity
96%
SMILES
C1=CC=NC(=C1)C2=NC(=CC=C2)C3=CC=CC=N3.O.O.Cl[Pt]Cl
InChIKey
WEBUYGBVKZYTMT-UHFFFAOYSA-L
H-Bond Donor
2
H-Bond Acceptor
5
Safty Description
S26
Hazard Statements
Xi: Irritant;
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1Pivotal Role of a Pentacoordinate (3)MC State on the Photocleavage Efficiency of a Thioether Ligand in Ruthenium(II) Complexes: A Theoretical Mechanistic Study.

Göttle AJ1, Alary F1, Boggio-Pasqua M1, Dixon IM1, Heully JL1, Bahreman A2, Askes SH2, Bonnet S2.

Inorg Chem. 2016 May 2;55(9):4448-56. doi: 10.1021/acs.inorgchem.6b00268. Epub 2016 Apr 7.

A mechanistic study of the photocleavage of the methylthioethanol ligand (Hmte) in the series of ruthenium complexes [Ru(tpy)(N-N)(Hmte)](2+) (tpy = 2,2':6',2″-terpyridine, N-N = bpy (2,2'-bipyridine), biq (2,2'-biquinoline), dcbpy (6,6'-dichloro-2,2'-bipyridine), dmbpy (6,6'-dimethyl-2,2'-bipyridine)) was performed using density functional theory. These studies reveal the decisive role of two quasi-degenerate triplet metal-centered states, denoted (3)MChexa and (3)MCpenta, on the lowest triplet potential energy surface. Read More

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Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA