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Home > Product > Precious Metal Catalyst > Dichloro(1,5-cyclooctadiene)platinum(II)

Dichloro(1,5-cyclooctadiene)platinum(II) | CAS Number: 12080-32-9

Catalog Number
ACM12080329
Product Name
Dichloro(1,5-cyclooctadiene)platinum(II)
Structure
CAS Number
12080-32-9
EC Number
235-144-5
MDL Number
MFCD00012413
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;dichloroplatinum
Synonyms
(1,5-Cyclooctadiene)platinum dichloride
Molecular Weight
374.16
Exact Mass
368.96500
Molecular Formula
C8H12Cl2Pt
Boiling Point
153.5ºC at 760 mmHg
Melting Point
285 °C (dec.)(lit.)
Flash Point
31.7ºC
Purity
Pt ≥52.1%
Appearance
dark yellow powder
SMILES
C1CC=CCCC=C1.Cl[Pt]Cl
InChIKey
VVAOPCKKNIUEEU-PHFPKPIQSA-L
Symbol
GHS07
Safty Description
Warning
Hazard Statements
H315-H319-H335
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1The Effect of Substituents at Lewis Acidic Bismuth(III) Centers on Its Propensity to Bind a Noble Metal Donor.

Tschersich C1, Hoof S1, Frank N1, Herwig C1, Limberg C1.

Inorg Chem. 2016 Feb 15;55(4):1837-42. doi: 10.1021/acs.inorgchem.5b02740. Epub 2016 Feb 4.

To investigate the effect of X in ambiphilic compounds BiX(o-PPh2-C6H4)2, PBiP-X, on metallophilic Pt-Bi interactions in its PtCl2 complexes two new derivatives PBiP-Me and PBiP-C6F5 were synthesized. Reaction with dichloro(1,5-cyclooctadiene)platinum(II) led to the platinum(II) complexes [PtCl2(PBiP-Me)], 3, and [PtCl2(PBiP-C6F5)], 4, which together with the halide [PtCl2(PBiP-Cl)], 2, reported previously, establish a series of related PBiP-X complexes differing only in X. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA