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Home > Product > Material & Chemicals > Polymer/Macromolecule > Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium(ii)

Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium(ii) | CAS Number: 900169-53-1

Catalog Number
ACM900169531
Product Name
Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium(ii)
Structure
CAS Number
900169-53-1
IUPAC Name
benzylidene-[1,3-bis(2,4,6-trimethylphenyl)imidazolidin-2-ylidene]-dichlororuthenium;3-bromopyridine
Synonyms
Dichloro[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene](benzylidene)bis(3-bromopyridine)ruthenium(II);[1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]bis(2-bromopyridine)dichloro(phenylmethylene)ruthenium;Dichloro[1,3-bis(2,4,6-trimethylpheny
Molecular Weight
883
Exact Mass
883.01200
Molecular Formula
C38H38Br2Cl2N4Ru-2
Purity
96%
InChIKey
YDOACSUCKSODBO-UHFFFAOYSA-L
H-Bond Donor
0
H-Bond Acceptor
4
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1Characterization and dynamics of substituted ruthenacyclobutanes relevant to the olefin cross-metathesis reaction.

Wenzel AG1, Blake G, VanderVelde DG, Grubbs RH.

J Am Chem Soc. 2011 Apr 27;133(16):6429-39. doi: 10.1021/ja2009746. Epub 2011 Mar 31.

The reaction of the phosphonium alkylidene [(H(2)IMes)RuCl(2)=CHP(Cy)(3))](+) BF(4)(-) with propene, 1-butene, and 1-hexene at -45 °C affords various substituted, metathesis-active ruthenacycles. These metallacycles were found to equilibrate over extended reaction times in response to decreases in ethylene concentrations, which favored increased populations of α-monosubstituted and α,α'-disubstituted (both cis and trans) ruthenacycles. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA