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Diborane | CAS Number: 19287-45-7

Catalog Number
ACM19287457
Product Name
Diborane
Structure
CAS Number
19287-45-7
Synonyms
B2H6;Boron hydride (B2H6);Diborane(6);diborane,b2h6;diboranemixtures;Diboron hexahydride;Diboronhexahydride;dlborane
Molecular Weight
25.65
Molecular Formula
B2H4
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1Facile Access to Unprecedented Electron-Precise Monohydrodiboranes(4), cis-1,2-Dihydrodiboranes(4) and a 1,1-Dihydrodiborane(5).

Arrowsmith M, Braunschweig H1, Radacki K, Thiess T, Turkin A.

Chemistry. 2016 Dec 9. doi: 10.1002/chem.201605270. [Epub ahead of print]

2,3-bis(dimethylamino)-substituted B2N2C2 heterocycles underwent selective dimethylamino/hydride exchange with either one or two equivalents of BH3∙SMe2 to yield the corresponding cyclic monohydrido- or (cis)1,2-dihydridodiboranes(4), respectively. Upon either heating or irradiation in solution, the latter underwent ring-contraction to the corresponding five-membered BN2C2 heterocycles, while irradiation of the 1,2-dimethylamidoethene-supported 1,2-dihydridodiborane(4) in the presence of PEt3 yielded an unprecedented unsymmetrical 1,1-dihydrodiborane(5) phosphine adduct. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA