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Home > Product > Heterocyclic Organic Compounds > Cyclopropylboronic acid pinacol ester

Cyclopropylboronic acid pinacol ester | CAS Number: 126689-01-8

Catalog Number
ACM126689018
Product Name
Cyclopropylboronic acid pinacol ester
Structure
CAS Number
126689-01-8
Synonyms
CYCLOPROPYLBORONIC ACID PINACOL ESTER;2-CYCLOPROPYL-4,4,5,5-TETRAMETHYL-1,3,2-DIOXABOROLANE;2-CYCLOPROPYLBORONIC ACID, PINACOL ESTER;AKOS BRN-0606;2-Cyclopropyl-4,4,5,5-tetramethyl-1,3,2-;(4,4,5,5-Tetramethyl-1,3,2-dioxaborolan-2-yl)cyclopropane;Cycloprop
Molecular Weight
168.04
Molecular Formula
C9H17BO2
Purity
97%
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1Applications of 1-alkenyl-1,1-heterobimetallics in the stereoselective synthesis of cyclopropylboronate esters, trisubstituted cyclopropanols and 2,3-disubstituted cyclobutanones.

Hussain MM1, Li H, Hussain N, UreƱa M, Carroll PJ, Walsh PJ.

J Am Chem Soc. 2009 May 13;131(18):6516-24. doi: 10.1021/ja900147s.

1-Alkenyl-1,1-heterobimetallics are potentially very useful in stereoselective organic synthesis but are relatively unexplored. Introduced herein is a practical application of 1-alkenyl-1,1-heterobimetallic intermediates in the synthesis of versatile cyclopropyl alcohol boronate esters, which are valuable building blocks. Thus, hydroboration of 1-alkynyl-1-boronate esters with dicyclohexylborane generates 1-alkenyl-1,1-diboro species. Read More

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Tel:1-201-478-8534
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