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Home > Product > Metal Organics > Organic Copper > Copper(ii)trifluoromethanesulfonate

Copper(ii)trifluoromethanesulfonate | CAS Number: 34946-82-2

Catalog Number
ACM34946822
Product Name
Copper(ii)trifluoromethanesulfonate
Structure
CAS Number
34946-82-2
Synonyms
TRIFLUOROMETHANESULFONIC ACID COPPER SALT;TRIFLUOROMETHANESULFONIC ACID COPPER(II) SALT;COPPER TRIFLATE;COPPER(II) TRIFLATE;COPPER(II) TRIFLUOROMETHANESULFONATE;COPPER(II) TRIFLUOROMETHANESULPHONATE;CUPRIC TRIFLUOROMETHANESULFONATE;Copper (II) trifluorome
Molecular Weight
361.68
Molecular Formula
C2CuF6O6S2
Purity
98%
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1Copper-catalyzed C(sp3)-OH cleavage with concomitant C-C coupling: synthesis of 3-substituted isoindolinones.

Rao HS1, Rao AV.

J Org Chem. 2015 Feb 6;80(3):1506-16. doi: 10.1021/jo502446k. Epub 2015 Jan 23.

Copper(II) trifluoromethanesulfonate (Cu(OTf)2) efficiently catalyzes the C-C coupling of 3-hydoxyisoindolinones with a variety of aryl-, heteroaryl-, and alkenylboronic acids to furnish C(3) aryl-, heteroaryl-, and alkenyl-substituted isoindolinones. The coupling reactions work smoothly in 1,2-dicholoroethane (DCE) reflux, to effect both inter- and intramolecular versions. This is the first report on C(sp(3))-OH cleavage with concomitant C-C coupling. Read More

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Tel:1-201-478-8534
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