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Copper(ii)fluoride | CAS Number: 7789-19-7

Catalog Number
ACM7789197
Product Name
Copper(ii)fluoride
Structure
CAS Number
7789-19-7
Molecular Weight
101.5428064
Molecular Formula
CuF2
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1Aryl(triethyl)silanes for Biaryl and Teraryl Synthesis by Copper(II)-Catalyzed Cross-Coupling Reaction.

Komiyama T1, Minami Y2, Hiyama T2.

Angew Chem Int Ed Engl. 2016 Dec 19;55(51):15787-15791. doi: 10.1002/anie.201608667. Epub 2016 Nov 16.

Aryl(triethyl)silanes are found to undergo cross-coupling with iodoarenes in the presence of catalytic amounts of CuBr2 and Ph-Davephos, as well as cesium fluoride as a stoichiometric base. Because the silicon reagents are readily accessible through catalytic C-H silylation of aromatic substrates, the net transformation allows coupling of aromatic hydrocarbons with iodoarenes via triethylsilylation.© 2016 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA