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Home > Product > Metal Organics > Organic Copper > Copper(ii)ethoxide

Copper(ii)ethoxide | CAS Number: 2850-65-9

Catalog Number
ACM2850659
Product Name
Copper(ii)ethoxide
Structure
CAS Number
2850-65-9
Synonyms
COPPER(II) ETHOXIDE
Molecular Weight
153.67
Molecular Formula
C4H10CuO2
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1Electronic Structure of a Cu(II)-Alkoxide Complex Modeling Intermediates in Copper-Catalyzed Alcohol Oxidations.

Hayes EC1, Porter TR1, Barrows CJ1, Kaminsky W1, Mayer JM1, Stoll S1.

J Am Chem Soc. 2016 Mar 30;138(12):4132-45. doi: 10.1021/jacs.5b13088. Epub 2016 Mar 18.

In the copper-catalyzed oxidation of alcohols to aldehydes, a Cu(II)-alkoxide (Cu(II)-OR) intermediate is believed to modulate the αC-H bond strength of the deprotonated substrate to facilitate the oxidation. As a structural model for these intermediates, we characterized the electronic structure of the stable compound Tp(tBu)Cu(II)(OCH2CF3) (Tp(tBu) = hydro-tris(3-tert-butyl-pyrazolyl)borate) and investigated the influence of the trifluoroethoxide ligand on the electronic structure of the complex. Read More

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Tel:1-201-478-8534
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