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Home > Product > Material & Chemicals > Micro/NanoElectronics > Copper(ii)acetate monohydrate

Copper(ii)acetate monohydrate | CAS Number: 66923-66-8

Catalog Number
ACM66923668
Product Name
Copper(ii)acetate monohydrate
Structure
CAS Number
66923-66-8
Synonyms
COPPER (II) ACETATE, HYDROUS;COPPER(II) ACETATE HYDRATE;COPPER(II) ACETATE-1-HYDRATE;COPPER(+2)ACETATE MONOHYDRATE;COPPER ACETATE MONOHYDRATE;COPPER ACETATE;CUPRIC ACETATE H2O;CUPRIC ACETATE 1-HYDRATE
Molecular Weight
199.65
Molecular Formula
C4H8CuO5
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1Ligand-Enabled, Copper-Promoted Regio- and Chemoselective Hydroxylation of Arenes, Aryl Halides, and Aryl Methyl Ethers.

Singh BK1,2, Jana R1,2.

J Org Chem. 2016 Feb 5;81(3):831-41. doi: 10.1021/acs.joc.5b02302. Epub 2016 Jan 25.

We report here a practical method for the ortho C-H hydroxylation of benzamides with inexpensive copper(II) acetate monohydrate and a pyridine ligand. An intra- and intermolecular ligand combination was explored to achieve regio- and chemoselective hydroxylation. Interestingly, typical regiochemical scrambling associated with the C-H activation was further resolved by introducing a ligand-directed ortho hydroxylation of haloarenes and aryl methyl ethers.

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA