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Home > Product > Metal Organics > Organic Copper > Copper(i)hexafluoro-2,4-pentanedionate-cyclooctadiene complex

Copper(i)hexafluoro-2,4-pentanedionate-cyclooctadiene complex | CAS Number: 86233-74-1

Catalog Number
ACM86233741
Product Name
Copper(i)hexafluoro-2,4-pentanedionate-cyclooctadiene complex
Structure
CAS Number
86233-74-1
Synonyms
COPPER I HEXAFLUOROPENTANEDIONATE CYCLOOCTADIENE COMPLEX;COPPER(I) HEXAFLUORO-2,4-PENTANEDIONATE-CYCLOOCTADIENE COMPLEX;Copper(I) hexafluoroacetylacetonate cyclooctadiene complex;copper(i) hexafluoroacetylacetonate;Copper(I) hexafluoro-2,4-pentanedionate-
Molecular Weight
378.78
Molecular Formula
C13H13CuF6O2 4*
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1Gas-phase structure of (1,1,1,5,5,5-hexafluoro-2,4-pentanedionato)(eta(2)-1,5-cyclooctadiene)copper(I), Cu(1,5-cod)(hfac), an important precursor for vapor deposition of copper.

Hnyk D1, Bühl M, Brain PT, Robertson HE, Rankin DW.

J Am Chem Soc. 2002 Jul 10;124(27):8078-84.

The molecular structure of Cu(1,5-cod)(hfac) in the gas phase has been determined by electron diffraction, restrained by parameters calculated ab initio (MP2/AE1 level) or using Density Functional Theory (BP86/AE1 level). The most stable structure is one in which one olefinic group of the cyclooctadiene ligand is coordinated to the square-planar copper atom [refined Cu-C distances 194.0(13) and 194. Read More

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