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Cobalt thiocyanate | CAS Number: 3017-60-5

Catalog Number
ACM3017605
Product Name
Cobalt thiocyanate
Structure
CAS Number
3017-60-5
Synonyms
thiocyanicacid,cobalt(2++)salt;COBALTOUS THIOCYANATE;COBALT THIOCYANATE;COBALT(II) THIOCYANATE;cobalt dithiocyanate;Cobalt(II) thiopcyanate;Cobaltthiopcyanate;Cobalt thiocyanate hydrate
Molecular Weight
175.1
Molecular Formula
C2CoN2S2
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1Thermodynamically metastable thiocyanato coordination polymer that shows slow relaxations of the magnetization.

Werner J1, Rams M, Tomkowicz Z, Runčevski T, Dinnebier RE, Suckert S, Näther C.

Inorg Chem. 2015 Mar 16;54(6):2893-901. doi: 10.1021/ic503029t. Epub 2015 Mar 5.

Reaction of cobalt thiocyanate with 4-acetylpyridine leads to the formation of [Co(NCS)2(4-acetylpyridine)2]n (3/I). In its crystal structure the Co cations are connected by pairs of μ-1,3-bridging thiocyanato ligands into dimers that are further connected into layers by single anionic ligands. DTA-TG measurements of Co(NCS)2(4-acetyl-pyridine)4 (1) led to the formation of 3/I. In contrast, when the hydrate Co(NCS)2(4-acetyl-pyridine)2(H2O)2 (2) is decomposed, a mixture of 3/I and a thermodynamically metastable form 3/II is obtained. Read More

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Tel:1-201-478-8534
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