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Home > Product > Precious Metal Catalyst > cis-Dichlorobis(diethyl sulfide)platinum(II)

cis-Dichlorobis(diethyl sulfide)platinum(II) | CAS Number: 15442-57-6

Catalog Number
ACM15442576
Product Name
cis-Dichlorobis(diethyl sulfide)platinum(II)
Structure
CAS Number
15442-57-6
MDL Number
MFCD00050943
Synonyms
cis-Dichlorobis(1,1′-thiobisethane)platinum
Molecular Weight
446.36
Molecular Formula
[Pt(C4SH10)2]Cl2
Melting Point
105 °C(lit.)
Purity
Pt 43%
Appearance
yellow powder
Symbol
GHS07
Safty Description
Warning
Hazard Statements
H315-H319-H335
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1Cis/trans isomers of PtX2L2 (X = halogen, L = neutral ligand); the crystal structure of trans-dichlorobis(dimethyl sulfide)platinum(II) and the pressure dependence of its unit-cell dimensions.

Hansson C1, Carlson S, Giveen D, Johansson M, Yong S, Oskarsson A.

Acta Crystallogr B. 2006 Jun;62(Pt 3):474-9. Epub 2006 May 15.

trans-PtCl(2)(dms)(2) (dms is dimethyl sulfide) crystallizes in the space group P2(1)/n and adopts the molecular point group C(i), which is the most frequently occurring point group for trans-PtX(2)L(2) complexes (78%), as observed in the Cambridge Structural Database (CSD; 2005 release), followed by C(1) (16%). Density functional theory calculations show that the observed geometry for trans-PtCl(2)(dms)(2) has slightly higher energy than the most favorable geometry in the point group C(2h), but this geometry would require a space group that hampers close packing, thus showing that intermolecular forces determine the point group for the title compound. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA