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Home > Product > Material & Chemicals > Organic & Printed Electronics > cis-Bis(2,2-bipyridine)dichlororuthenium(ii)hydrate

cis-Bis(2,2-bipyridine)dichlororuthenium(ii)hydrate | CAS Number: 98014-14-3

Catalog Number
ACM98014143
Product Name
cis-Bis(2,2-bipyridine)dichlororuthenium(ii)hydrate
Structure
CAS Number
98014-14-3
Synonyms
CIS-BIS(2,2-BIPYRIDINE)DICHLORORUTHENIUM(II) HYDRATE;CIS-BIS-(2,2-BIPYRIDINE) RUTHENIUM (II) CHLORIDE, HYDRATE;CIS-DICHLOROBIS(2,2-BIPYRIDINE)-RUTHENIUM(II) HYDRATE;cis-Bis(2,2-bipyridine)dichlororuthenium(II)hydrate,97%;cis-BIS(2,2-BIPYRIDINE) RUTHENIUM
Molecular Weight
502.36
Molecular Formula
C20H18Cl2N4ORu
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1Structural, electrochemical and photophysical properties of an exocyclic di-ruthenium complex and its application as a photosensitizer.

Salpage SR1, Paul A, Som B, Banerjee T, Hanson K, Smith MD, Vannucci AK, Shimizu LS.

Dalton Trans. 2016 Jun 21;45(23):9601-7. doi: 10.1039/c6dt01377e. Epub 2016 May 24.

The reaction of cis-bis(2,2'-bipyridine)dichlororuthenium(ii) hydrate with a conformationally mobile bipyridyl macrocycle afforded [(bpy)2Ru(μ-L)Ru(bpy)2]Cl4·6H2O, a bridged di-Ru complex. Single crystal X-ray diffraction showed the macrocyclic ligand adopting a bowl-like structure with the exo-coordinated Ru(ii) centers separated by 7.29 Å. Photophysical characterization showed that the complex absorbs in the visible region (λmax = 451 nm) with an emission maximum at 610 nm (τ = 706 ns, ΦPL = 0. Read More

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Tel:1-201-478-8534
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