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Chromyl chloride | CAS Number: 14977-61-8

Catalog Number
ACM14977618
Product Name
Chromyl chloride
Structure
CAS Number
14977-61-8
Synonyms
CHROMIC OXYCHLORIDE;CHROMIUM DIOXYCHLORIDE;CHROMYL CHLORIDE;CHROMIUM OXYCHLORIDE;CHLOROCHROMIC ANHYDRIDE;(beta-4)-chromiu;chlorochromicanhydride[qr];Chlorure de chromyle
Molecular Weight
154.9
Molecular Formula
Cl2CrO2
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1Density functional theory study of the mechanisms of oxidation of ethylene by chromyl chloride.

Tia R1, Adei E.

Inorg Chem. 2009 Dec 7;48(23):11434-43. doi: 10.1021/ic901648y.

The mechanistic pathways for the formation of epoxide, 1,2-dichloroethane, 1,2-chlorohydrin, acetaldehyde, and vinyl alcohol precursors in the oxidation of ethylene by chromyl chloride has been studied using hybrid density functional theory at the B3LYP/LACVP* level of theory. The formation of the epoxide precursor (Cl(2)(O)Cr-OC(2)H(4)) was found to take place via initial [2 + 2] addition of ethylene across the Cr=O bonds of CrO(2)Cl(2) to form a chromaoxetane intermediate. Read More

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Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA