Paidi AK1, Devi RN, Vidyasagar K.
Dalton Trans. 2015 Oct 21;44(39):17399-408. doi: 10.1039/c5dt02618k. Epub 2015 Sep 21.Eight new quaternary vanadates of niobium and tantalum, AMV2O8 (A = K, Rb, Tl, Cs; M = Nb, Ta), have been prepared by solid state reactions and structurally characterized by single crystal and powder X-ray diffraction (XRD) techniques. The two cesium compounds, unlike the known CsSbV2O8 with a layered yavapaiite structure, have a new three-dimensional structure and the other six compounds possess the known KSbV2O8 structure type. Read More