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Home > Product > Material & Chemicals > Metal & Ceramic Materials > Cerium(iii)chloride heptahydrate

Cerium(iii)chloride heptahydrate | CAS Number: 18618-55-8

Catalog Number
ACM18618558
Product Name
Cerium(iii)chloride heptahydrate
Structure
CAS Number
18618-55-8
Synonyms
CERIUM(+3)CHLORIDE HEPTAHYDRATE;CEROUS CHLORIDE HEPTAHYDRATE;CERIUM CHLORIDE HEPTAHYDRATE;CERIUM(III) CHLORIDE HEPTAHYDRATE;CERIUM(III) CHLORIDE HYDRATE;CERIUM (III) CHLORIDE, HYDROUS;Ceriumchloridehydrate;Cerium(III) chloride heptahydrate, 99.9% metals b
Molecular Weight
372.58
Molecular Formula
CeCl3H14O7
Purity
99.9%
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1Efficient preparation of 2-indolyl-1-nitroalkane derivatives employing nitroalkenes as versatile Michael acceptors: new practical linear approach to alkyl 9h-beta-carboline-4-carboxylate.

Bartoli G1, Bosco M, Giuli S, Giuliani A, Lucarelli L, Marcantoni E, Sambri L, Torregiani E.

J Org Chem. 2005 Mar 4;70(5):1941-4.

The combination of cerium(III) chloride heptahydrate and sodium iodide supported on silica gel is known to promote Michael-type additions. Continuing our work on solvent-free conditions, the CeCl3.7H2O-NaI-SiO2 system catalyzes the addition of a variety of indoles and nitroalkenes, giving 2-indolyl-1-nitroalkane derivatives in good yields. Development of this method has resulted in a new protocol for the synthesis of 4-substituted beta-carbolines.

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