(S,S)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane

CAS
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CAS
97858-62-3
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Catalog Number

ACM97858623

Product Name

(S,S)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane

Structure

CAS

97858-62-3

Category

Heterocyclic Organic Compound

Synonyms

Ethylenebis[(S)-(o-anisyl)(phenyl)phosphine]; MFCD05863547; (S,S)-DIPAMP, >=95%; AB1011200; (1S,2S)-(+)-Bis[(2-methoxyphenyl)phenylphosphino]ethane; UNII-HS6F5EW3U6; OR310819; ST24036672;

IUPAC Name

(S)-(2-methoxyphenyl)-[2-[(2-methoxyphenyl)-phenylphosphanyl]ethyl]-phenylphosphane;

Molecular Weight

458.478g/mol

Molecular Formula

C28H28O2P2;

Canonical SMILES

COC1=CC=CC=C1P(CCP(C2=CC=CC=C2)C3=CC=CC=C3OC)C4=CC=CC=C4;

InChI

InChI=1S/C28H28O2P2/c1-29-25-17-9-11-19-27(25)31(23-13-5-3-6-14-23)21-22-32(24-15-7-4-8-16-24)28-20-12-10-18-26(28)30-2/h3-20H,21-22H2,1-2H3/t31-,32-/m0/s1;

InChI Key

QKZWXPLBVCKXNQ-ACHIHNKUSA-N;

Application

Rhodium DIPAMP catalysts have shown high activity and enantioselectivity in the asymmetric hydrogenation of enamides, enol acetates and olefins.

Complexity

472

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

Exact Mass

458.156g/mol

H-Bond Acceptor

Heavy Atom Count