5,10,15,20-Tetrakis(3,5-dimethoxyphenyl)porphyrin

Catalog Number

ACM74684347

Product Name

5,10,15,20-Tetrakis(3,5-dimethoxyphenyl)porphyrin

Structure

CAS

74684-34-7

Category

Heterocyclic Organic Compound

Description

Alfa Chemistry offers 5,10,15,20-Tetrakis(3,5-dimethoxyphenyl)porphyrin products for various research purposes. Please contact us by email if you do not find the specification you are looking for on this page.

Synonyms

5,10,15,20-Tetrakis(3,5-dimethoxyphenyl)-21H,23H-porphine

IUPAC Name

5,10,15,20-tetrakis(3,5-dimethoxyphenyl)-21,23-dihydroporphyrin;

Molecular Weight

854.96

Molecular Formula

C52H46N4O8

Canonical SMILES

COC1=CC(=CC(=C1)C2=C3C=CC(=C(C4=NC(=C(C5=CC=C(N5)C(=C6C=CC2=N6)C7=CC(=CC(=C7)OC)OC)C8=CC(=CC(=C8)OC)OC)C=C4)C9=CC(=CC(=C9)OC)OC)N3)OC;

InChI

InChI=1S/C52H46N4O8/c1-57-33-17-29(18-34(25-33)58-2)49-41-9-11-43(53-41)50(30-19-35(59-3)26-36(20-30)60-4)45-13-15-47(55-45)52(32-23-39(63-7)28-40(24-32)64-8)48-16-14-46(56-48)51(44-12-10-42(49)54-44)31-21-37(61-5)27-38(22-31)62-6/h9-28,53,56H,1-8H3;

InChI Key

YNXRFPUCCCJMPX-UHFFFAOYSA-N;

Appearance

Dark red to Dark purple to Dark blue powder to crystal

Application

The porphyrin metal complexes are important in-vivo, because they are included in chlorophyll functioning photo absorption and photo electron transfer for photosynthesis, and also included in heme transporting oxygen in blood. In addition, porphyrinato metal complexes are useful for photoelectron functional materials, metal complex catalysts and molecular electrical conductors.

Absorbance

(E1%1cm) min. 5500(CHCl2, 418.0 to 422.0 nm)

Absorption Wavelength

(max.) 420(CH2Cl2) nm

Complexity

1200

Condition To Avoid

Air Sensitive

Covalently-Bonded Unit Count

1

Exact Mass

854.332g/mol

Features And Benefits

Chemical modifications of substituted groups, metal centers, and axial ligands on the porphyrinato metal complexes show various functionalities. Normal porphyrin complexes have sharp absorptions, around 400-500 nm, and the Q band around 500-700 nm which is a relatively weak absorption. Molar absorption coefficients of the Soret band are up to the order of 106 M/cm. The chlorophyll and porphyrinato zinc complexes hardly show energy relaxation of absorbed light, but easily show photoelectron transfer.

H-Bond Acceptor

10

H-Bond Donor

2

Heavy Atom Count

64

MDL Number

MFCD02093501

Monoisotopic Mass

854.332g/mol

Physical State

(20 deg.C) Solid

Rotatable Bond Count

12

Storage Conditions

Store under inert gas

Topological Polar Surface Area

131A^2

MSDS

COA

Spec Sheet