cBRIDP

Catalog Number

ACM742103271

Product Name

cBRIDP

Structure

CAS

742103-27-1

Category

Heterocyclic Organic Compound

Synonyms

di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphine; di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl) phosphine; Di-t-butyl(2,2-diphenyl-1-methylcyclopropyl)phosphine cBRIDP; Di-tert-butyl(1-methyl-2,2-diphenylcyclopropyl)phosphane; SCHEMBL377365; 742103-27-1; di-t-butyl-(2,2-diphenyl-1-methylcyclopropyl)-phosphine; di-t-butyl (2,2-diphenyl-1-methyl-1-cyclopropyl)phosphine; (1-Methyl-2,2-diphenylcyclopropyl)di-tert-butylphosphine;

IUPAC Name

ditert-butyl-(1-methyl-2,2-diphenylcyclopropyl)phosphane;

Molecular Weight

352.502g/mol

Molecular Formula

C24H33P;

Canonical SMILES

CC1(CC1(C2=CC=CC=C2)C3=CC=CC=C3)P(C(C)(C)C)C(C)(C)C;

InChI

InChI=1S/C24H33P/c1-21(2,3)25(22(4,5)6)23(7)18-24(23,19-14-10-8-11-15-19)20-16-12-9-13-17-20/h8-17H,18H2,1-7H3;

InChI Key

QMLPJDVGNRHGJQ-UHFFFAOYSA-N;

Application

Ligand effective for many classes of palladium-catalyzed coupling of aryl halides, including the Miyaura-Suzuki, Buchwald- Hartwig, Sonogashira, Heck, aryl etherification, and carbonylation reactions.

Ligand used in the palladium catalyzed Suzuki-Miyaura coupling of aryl boronic acids.

Ligand employed in the palladium-catalyzed Buchwald-Hartwig aryl amination reaction.

Complexity

422

Covalently-Bonded Unit Count

1

Exact Mass

352.232g/mol

Heavy Atom Count

25

Monoisotopic Mass

352.232g/mol

Rotatable Bond Count

5

Topological Polar Surface Area

0A^2

Undefined Atom Stereocenter Count

1

MSDS

COA

Spec Sheet