(S)-7,7'-bis(diphenylphosphino)-1,1'-spirobiindane((S)-SDP)

Catalog Number

ACM528521860

Product Name

(S)-7,7'-bis(diphenylphosphino)-1,1'-spirobiindane((S)-SDP)

Structure

CAS

528521-86-0

Category

Heterocyclic Organic Compound

Synonyms

(S)-SDP, >=95%; 7,7'-Bis(diphenylphosphino)-1,1'-spirobiindan; SCHEMBL29269; (R)-(+)-7,7'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-1,1'-spirobiindane; (R)-SDP; (4'-diphenylphosphino-3,3'-spirobi[1,2-dihydroindene]-4-yl)-diphenylphosphine; (S)-7,7 inverted exclamation marka-Bis(diphenylphosphino)-1,1 inverted exclamation marka-spirobiindane; A829281; FT-0729696; AKOS015899950;

IUPAC Name

(4'-diphenylphosphanyl-3,3'-spirobi[1,2-dihydroindene]-4-yl)-diphenylphosphane;

Molecular Weight

588.671g/mol

Molecular Formula

C41H34P2;

Canonical SMILES

C1CC2(CCC3=C2C(=CC=C3)P(C4=CC=CC=C4)C5=CC=CC=C5)C6=C1C=CC=C6P(C7=CC=CC=C7)C8=CC=CC=C8;

InChI

InChI=1S/C41H34P2/c1-5-17-33(18-6-1)42(34-19-7-2-8-20-34)37-25-13-15-31-27-29-41(39(31)37)30-28-32-16-14-26-38(40(32)41)43(35-21-9-3-10-22-35)36-23-11-4-12-24-36/h1-26H,27-30H2;

InChI Key

DKZNVWNOOLQCMJ-UHFFFAOYSA-N;

Application

Ligands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity.

Ligands used for palladium-catalyzed asymmetric allylic alkylations.

Complexity

766

Covalently-Bonded Unit Count

1

Exact Mass

588.214g/mol

Heavy Atom Count

43

Monoisotopic Mass

588.214g/mol

Rotatable Bond Count

6

Topological Polar Surface Area

0A^2

MSDS

COA

Spec Sheet