Lithium tris(S-(-)-1,1'-binaphthyl-2,2'-diolato)yttrate(III) tetrahydrofuran adduct, min. 97%

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500995-67-5
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Catalog Number

ACM500995675

Product Name

Lithium tris(S-(-)-1,1'-binaphthyl-2,2'-diolato)yttrate(III) tetrahydrofuran adduct, min. 97%

Structure

CAS

500995-67-5

Category

Heterocyclic Organic Compound

Synonyms

500995-67-5;Lithium tris(S-(-)-1,1'-binaphthyl-2,2'-diolato)yttrate(III) tetrahydrofuran adduct;MFCD07781990;SC10896;Lithium tris(s-(-)-1,1'-binaphthyl-2,2'-diolato)yttrate(iii);LITHIUM TRIS(S-(-)-1,1'-BINAPHTHYL-2,2'-DIOLATO)YTTRATE (III);

IUPAC Name

trilithium;1-(2-hydroxynaphthalen-1-yl)naphthalen-2-olate;yttrium;

Molecular Weight

965.692g/mol

Molecular Formula

C60H39Li3O6Y;

Canonical SMILES

[Li+].[Li+].[Li+].C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)[O-])O.C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)[O-])O.C1=CC=C2C(=C1)C=CC(=C2C3=C(C=CC4=CC=CC=C43)[O-])O.[Y];

InChI

InChI=1S/3C20H14O2.3Li.Y/c3*21-17-11-9-13-5-1-3-7-15(13)19(17)20-16-8-4-2-6-14(16)10-12-18(20)22;;;;/h3*1-12,21-22H;;;;/q;;;3*+1;/p-3;

InChI Key

AEDVYRBRQPAIFJ-UHFFFAOYSA-K;

Application

Catalyst used for the asymmetric cyano-ethoxycarbonylation reaction of aldehydes.

Catalyst used for the efficient, two-step conversion of α,β-unsaturated aldehydes to optically active γ-oxy-α,β-unsaturated nitriles.

Catalyst used for the asymmetric 1,4-addition of O-alkylhydroxyamine to enones.

Complexity

1320

Covalently-Bonded Unit Count

Exact Mass

965.229g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

965.229g/mol

Rotatable Bond Count

Topological Polar Surface Area