Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-binap]

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261948-85-0
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Catalog Number

ACM261948850

Product Name

Diacetato[(S)-(-)-2,2'-bis(diphenylphosphino)-1,1'-binaphthyl]ruthenium(II) Ru(OAc)2[(S)-binap]

Structure

CAS

261948-85-0

Category

Ruthenium series catalysts

Synonyms

(S)-Ru(OAc)2(BINAP); RU-BINAP; DIACETATO[(R)-(+)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II); 104713-03-3; Diacetato[(S)-(-)-2,2 inverted exclamation marka-bis(diphenylphosphino)-1,1 inverted exclamation marka-binaphthyl]ruthenium(II); 325146-81-4; DIACETATO[(R)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II); 261948-85-0; RU(OAC)2[(R)-BINAP]; DIACETATO[(S)-(-)-2,2'-BIS(DIPHENYLPHOSPHINO)-1,1'-BINAPHTHYL]RUTHENIUM(II);

IUPAC Name

acetic acid;[1-(2-diphenylphosphanylnaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;ruthenium;

Molecular Weight

843.862g/mol

Molecular Formula

C48H40O4P2Ru;

Canonical SMILES

CC(=O)O.CC(=O)O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=C(C4=CC=CC=C4C=C3)C5=C(C=CC6=CC=CC=C65)P(C7=CC=CC=C7)C8=CC=CC=C8.[Ru];

InChI

InChI=1S/C44H32P2.2C2H4O2.Ru/c1-5-19-35(20-6-1)45(36-21-7-2-8-22-36)41-31-29-33-17-13-15-27-39(33)43(41)44-40-28-16-14-18-34(40)30-32-42(44)46(37-23-9-3-10-24-37)38-25-11-4-12-26-38;2*1-2(3)4;/h1-32H;2*1H3,(H,3,4);;

InChI Key

XANQJWCSQJDBEA-UHFFFAOYSA-N;

Application

1. Catalyst system that exhibits very high catalytic activity and enantioselectivity in the

hydrogenation of a wide range of substrates.

2. Catalyst used in the synthesis of β-amino acids by hydrogenation.

Storage

2-8°C

Complexity

875

Covalently-Bonded Unit Count

Exact Mass

844.145g/mol

H-Bond Acceptor

H-Bond Donor

Heavy Atom Count

Monoisotopic Mass

844.145g/mol