Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II)

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Catalog Number
ACM25360321
Product Name
Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II)
Structure
Structure
CAS
25360-32-1
Category
Ruthenium series catalysts
Synonyms
25360-32-1;Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium(II);Carbonyldihydridotris(triphenylphosphine)ruthenium(II);Dihydridocarbonyltris(triphenylphosphine)ruthenium;C55H47OP3Ru;[(C6H5)3P]3Ru(CO)H2;AKOS024258165;Carbonyl(dihydrido)tris(triphenylphosphine)ruthenium (II);
IUPAC Name
formaldehyde;ruthenium dihydride;triphenylphosphane;
Molecular Weight
919.987g/mol
Molecular Formula
C55H49OP3Ru;
Canonical SMILES
C=O.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3.[RuH2];
InChI
InChI=1S/3C18H15P.CH₂O.Ru.2H/c3*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-2;;;/h3*1-15H;1H2;;;;
InChI Key
CEEYDFHDINQLNF-UHFFFAOYSA-N;
Application
Catalyst for the arylation (or alkenylation) of anthraquinone and PBI.

Catalytic C-C bond formation.

Transfer hydrogenative coupling of isoprene to alcohols or aldehydes.

Alkanes (and alkenes) from alcohols by tandem hydrogen transfer and condensation.

Catalyst for the conversion of primary alcohols and aldehydes into methyl esters.

Precatalyst for hydrogen production by means of alcohol dehydrogenation.
Storage
Refrigerator
Complexity
204
Covalently-Bonded Unit Count
5
Exact Mass
920.204g/mol
H-Bond Acceptor
1
Heavy Atom Count
60
Monoisotopic Mass
920.204g/mol
Rotatable Bond Count
9
Topological Polar Surface Area
17.1A^2
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