Catalog Number
ACM213343658
Product Name
(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(1,5-cyclooctadiene)rhodium(I) tetrafluoroborate, 98+% (S,S)-Me-BPE-Rh
Category
Heterocyclic Organic Compound
Synonyms
(-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)-rhodium(I) tetrafluoroborate; (-)-1,2-bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)-rhodium (I) tetrafluoroborate; PUBCHEM_12964417; LKVIVYCYPYTYSO-ASDDUFFSSA-N; 1,2-Bis[(2S,5S)-2,5-dimethylphospholano]ethane(cyclooctadiene)rhodium(I) tetrafluoroborate; (-)-1,2-Bis((2S,5S)-2,5-dimethylphospholano)ethane(cyclooctadiene)rhodium(I) tetrafluoroborate; (S,S)-Me-BPE-Rh;
IUPAC Name
(1Z,5Z)-cycloocta-1,5-diene;(2S,5S)-1-[2-[(2S,5S)-2,5-dimethylphospholan-1-yl]ethyl]-2,5-dimethylphospholane;rhodium;tetrafluoroborate;
Molecular Weight
556.219g/mol
Molecular Formula
C22H40BF4P2Rh-;
Canonical SMILES
[B-](F)(F)(F)F.CC1CCC(P1CCP2C(CCC2C)C)C.C1CC=CCCC=C1.[Rh];
InChI
InChI=1S/C14H28P2.C8H12.BF4.Rh/c1-11-5-6-12(2)15(11)9-10-16-13(3)7-8-14(16)4;1-2-4-6-8-7-5-3-1;2-1(3,4)5;/h11-14H,5-10H2,1-4H3;1-2,7-8H,3-6H2;;/q;;-1;/b;2-1-,8-7-;;/t11-,12-,13-,14-;;;/m0.../s1;
InChI Key
LKVIVYCYPYTYSO-ASDDUFFSSA-N;
Application
The DUPHOS family of catalysts is highly efficient for the asymmetric hydrogenation of various substituted acetamidoacrylates and enol acetates yielding products of high enantiomeric excesses. Efficient ligand for the asymmetric hydrogenation of tetrasubstituted enamides.
Covalently-Bonded Unit Count
4
Defined Atom Stereocenter Count
4
Defined Bond Stereocenter Count
2
Monoisotopic Mass
556.169g/mol
Topological Polar Surface Area
0A^2