RuCl[(R,R)-Tsdpen](mesitylene)

CAS
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CAS
174813-82-2
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Catalog Number

ACM174813822

Product Name

RuCl[(R,R)-Tsdpen](mesitylene)

Structure

CAS

174813-82-2

Category

Heterocyclic Organic Compound

Synonyms

174813-82-2;RuCl[(R,R)-TsDPEN](mesitylene);R0127;[(R,R)-N-(2-Amino-1,2-diphenylethyl)-p-toluenesulfonamide]chloro(mesitylene)ruthenium(II);Chloro(mesitylene)[(R,R)-N-(p-toluenesulfonyl)-1,2-diphenylethylenediamine]ruthenium(II);chloro[(1r,2r)-n-(p-toluenesulfonyl)-1,2-diphenylethanediamine](mesitylene)ruthenium(ii);

IUPAC Name

[(1R,2R)-2-amino-1,2-diphenylethyl]-(4-methylphenyl)sulfonylazanide;ruthenium(2+);1,3,5-trimethylbenzene;chloride;

Molecular Weight

622.186g/mol

Molecular Formula

C30H33ClN2O2RuS;

Canonical SMILES

CC1=CC=C(C=C1)S(=O)(=O)[N-]C(C2=CC=CC=C2)C(C3=CC=CC=C3)N.CC1=CC(=CC(=C1)C)C.[Cl-].[Ru+2];

InChI

InChI=1S/C21H21N2O2S.C9H12.ClH.Ru/c1-16-12-14-19(15-13-16)26(24,25)23-21(18-10-6-3-7-11-18)20(22)17-8-4-2-5-9-17;1-7-4-8(2)6-9(3)5-7;;/h2-15,20-21H,22H2,1H3;4-6H,1-3H3;1H;/q-1;;;+2/p-1/t20-,21-;;;/m1.../s1;

InChI Key

XBNBOGZUDCYNOJ-AGEKDOICSA-M;

Application

Catalyst used in the asymmetric transfer hydrogenation of ketones using formic acid-triethylamine mixture.

Storage

2-8°C

Complexity

566

Covalently-Bonded Unit Count

Defined Atom Stereocenter Count

Exact Mass

622.099g/mol