Rhodium(II) acetate dimer

Catalog Number

ACM15956282-1

Product Name

Rhodium(II) acetate dimer

Structure

CAS

15956-28-2

Category

Micro/NanoElectronics

Synonyms

Tetrakis-(mu-acetato)dirhodium

IUPAC Name

rhodium(2+);tetraacetate;

Molecular Weight

441.99

Molecular Formula

C8H12O8Rh2

Canonical SMILES

CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].CC(=O)[O-].[Rh+2].[Rh+2]

InChI

InChI=1S/4C2H4O2.2Rh/c4*1-2(3)4;/h4*1H3,(H,3,4);/q;2*+2/p-4

InChI Key

SYBXSZMNKDOUCA-UHFFFAOYSA-J

Melting Point

205 °C

Appearance

Fresh green crystal

Application

Catalyst for insertion into C-H and X-H bonds.

Catalyst for Ylide generation.

Doyle−Kirmse Reaction of Allylic Sulfides with Diazoalkane

Claisen rearrangement.

Epoxides from aldehydes.

Synthesis of aziridines from allylic N-tosyloxycarbamates.

Rh/NHC catalyzed direct intermolecular arylation of C-H bonds.

Chiral Bronsted acid-Rh catalyzed three component reactions of diazo compounds with alcohols and imines.

Rh-catalyzed cyclopropenations of ynamides.

Tandem asymmetric aza-Darzens/ring-opening reactions.

Storage

Store below +30°C.

Complexity

25.5

Covalently-Bonded Unit Count

6

Defined Atom Stereocenter Count

0

EC Number

240-084-8

Exact Mass

441.86421

H-Bond Acceptor

8

Heavy Atom Count

18

Hydrogen Bond Acceptor Count

8

Hydrogen Bond Donor Count

0

Monoisotopic Mass

441.86421

Rotatable Bond Count

0

Topological Polar Surface Area

161 Ų

UNII

NK3058Z56X

MSDS

COA

Spec Sheet