(S)-(-)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl

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Catalog Number
ACM134484369
Product Name
(S)-(-)-2-Diphenylphosphino-2'-methoxy-1,1'-binaphthyl
Structure
Structure
CAS
134484-36-9
Category
Heterocyclic Organic Compound
IUPAC Name
[1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl]-diphenylphosphane;
Molecular Weight
468.536g/mol
Molecular Formula
C33H25OP;
Canonical SMILES
COC1=C(C2=CC=CC=C2C=C1)C3=C(C=CC4=CC=CC=C43)P(C5=CC=CC=C5)C6=CC=CC=C6;
InChI
InChI=1S/C33H25OP/c1-34-30-22-20-24-12-8-10-18-28(24)32(30)33-29-19-11-9-13-25(29)21-23-31(33)35(26-14-4-2-5-15-26)27-16-6-3-7-17-27/h2-23H,1H3;
InChI Key
KRWTWSSMURUMDE-UHFFFAOYSA-N;
Application
Efficient catalyst for the enantioselective hydrosilyation of 1-alkenes to optically active 2-alcohols.

Ligand for palladium-catalyzed asymmetric reduction of allylic esters.

Ligand for the rhodium-catalyzed asymmetric arylation of imines with organostannanes.

Ligand for the rhodium-catalyzed asymmetric addition of aryland alkenylboronic acids to Isatins.
Complexity
634
Covalently-Bonded Unit Count
1
Exact Mass
468.164g/mol
H-Bond Acceptor
1
Heavy Atom Count
35
Monoisotopic Mass
468.164g/mol
Rotatable Bond Count
5
Topological Polar Surface Area
9.2A^2
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