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Calcium hydride | CAS Number: 7789-78-8

Catalog Number
ACM7789788
Product Name
Calcium hydride
Structure
CAS Number
7789-78-8
Synonyms
CALCIUM HYDRIDE;Cakium hydride;CaH2;Calcium hydride (CaH2);calciumhydride(cah2);Hydrolete;Hydrolith;Calciumhydridemesh
Molecular Weight
42.09
Molecular Formula
CaH2
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1Molecular Calcium Hydride: Dicalcium Trihydride Cation Stabilized by a Neutral NNNN-Type Macrocyclic Ligand.

Leich V1, Spaniol TP1, Maron L2, Okuda J3.

Angew Chem Int Ed Engl. 2016 Apr 4;55(15):4794-7. doi: 10.1002/anie.201600552. Epub 2016 Mar 8.

Hydrogenolysis of bis(triphenylsilyl)calcium containing the neutral NNNN-type macrocyclic amine ligand Me4TACD [Ca(Me4TACD)(SiPh3)2] (2), gave the cationic dinuclear calcium hydride [Ca2H3(Me4TACD)2](SiPh3) (3), characterized by NMR spectroscopy, single-crystal X-ray analysis, and DFT calculations. Compound 3 reacted with deuterium to give the deuteride [D3]-3.© 2016 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim.

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Email:
Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA