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Home > Product > Material & Chemicals > Polymer/Macromolecule > Butoxynol-5 carboxylic acid

Butoxynol-5 carboxylic acid | CAS Number: 104909-82-2

Catalog Number
ACM104909822
Product Name
Butoxynol-5 carboxylic acid
Structure
CAS Number
104909-82-2
IUPAC Name
4-tert-butylphenol;ethane-1,2-diol;2-hydroxyacetic acid
Synonyms
GLYCOLIC ACID ETHOXYLATE 4-TERT-BUTYLPHENYL ETHER;BUTOXYNOL-5 CARBOXYLIC ACID;BUTOXYNOL-19 CARBOXYLIC ACID;GLYCOLIC ACID ETHOXYLATE 4-TERT-BUTYLPHE NYL ETHER, MN CA. 380;tert.-Butylphenolethercarbonsure;Glycolic acid ethoxylate 4-tert-butylphenyl ether av
Molecular Weight
288.336760 [g/mol]
Exact Mass
288.15700
Molecular Formula
(CH3)3CC6H4(OCH2CH2)nOCH2CO2H,n~4
Flash Point
113ºC
Density
1.12 g/mL at 25ºC(lit.)
Purity
96%
InChIKey
OAGSUPHYBVNDLY-UHFFFAOYSA-N
H-Bond Donor
5
H-Bond Acceptor
6
Safty Description
26-36
Hazard Statements
Xi: Irritant;
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1Synthesis of α-(Pentafluorosulfanyl)- and α-(Trifluoromethyl)-substituted Carboxylic Acid Derivatives by Ireland-Claisen Rearrangement.

Dreier AL, Beutel B, Mück-Lichtenfeld C, Matsnev AV, Thrasher JS, Haufe G.

J Org Chem. 2016 Dec 30. doi: 10.1021/acs.joc.6b02805. [Epub ahead of print]

Earlier studies have shown that [3,3]-sigmatropic rearrangements of allyl esters are useful for the construction of fluorine-containing carboxylic acid derivatives. This paper describes the synthesis of 3-aryl-pent-4-enoic acid derivatives bearing either a pentafluorosulfanyl (SF5) or a trifluoromethyl (CF3) substituent in the 2-position by treatment of corresponding SF5 or CF3 acetates of p-substituted cinnamyl alcohols with trimethylamine followed by trimethylsilyl triflate (TMSOTf). Read More

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Tel:1-201-478-8534
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