Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%

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219770-99-7
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Catalog Number

ACM219770997

Product Name

Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II) dichloride, min. 97%

Structure

CAS

219770-99-7

Category

Ruthenium series catalysts

Synonyms

Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(IV) dichloride; SCHEMBL995991; BIS(TRICYCLOHEXYLPHOSPHINE)[(PHENYLTHIO)METHYLENE]RUTHENIUM(II) DICHLORIDE; Bis(tricyclohexylphosphine)[(phenylthio)methylene]ruthenium(II)dichloride; SC10225; 437767-65-2;

IUPAC Name

dichloro(phenylsulfanylmethylidene)ruthenium;tricyclohexylphosphane;

Molecular Weight

855.027g/mol

Molecular Formula

C43H72Cl2P2RuS;

Canonical SMILES

C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C1CCC(CC1)P(C2CCCCC2)C3CCCCC3.C1=CC=C(C=C1)SC=[Ru](Cl)Cl;

InChI

InChI=1S/2C18H33P.C7H6S.2ClH.Ru/c2*1-4-10-16(11-5-1)19(17-12-6-2-7-13-17)18-14-8-3-9-15-18;1-8-7-5-3-2-4-6-7;;;/h2*16-18H,1-15H2;1-6H;2*1H;/q;;;;;+2/p-2;

InChI Key

UDWHYAPPVOEOMP-UHFFFAOYSA-L;

Application

Metathesis catalyst, stable in air and can be used in aqueous media.

Catalyst of choice for the ring-opening metathesis polymerization of cycloolefins.

Catalyst concentration 2-3 times lower than comparable phenyl and vinyl substituted ruthenium carbenes.

Excellent initiator for solvent-free polymerization and control of initiation rates and gelation times.

Highly selective catalyst for the ring opening/cross-metathesis of norbornene derivatives.

Complexity

341

Covalently-Bonded Unit Count

Exact Mass

854.325g/mol

H-Bond Acceptor

Heavy Atom Count

Monoisotopic Mass

854.325g/mol

Rotatable Bond Count

Topological Polar Surface Area

25.3A^2