DaSilva JG1, Clérac R, Miller JS.
Inorg Chem. 2013 Oct 7;52(19):11677-83. doi: 10.1021/ic4021959. Epub 2013 Sep 23.The reversible hydrostatic pressure dependent DC magnetic behavior of the ferromagnetically ordered electron transfer salt [Fe(III)Cp2*](•+)[TCNE](•-) (Cp* = pentamethylcyclopentadienide; TCNE = tetracyanoethylene) was studied up to 12.2 kbar. A significant departure from the ambient pressure ferromagnetic behavior was observed under pressure. The temperature dependent magnetization data were typical of a ferromagnet at ambient pressure but exhibited an extreme reduction with increasing applied pressure, while metamagnetic-like behavior was evident in the field dependent magnetization data at 4. Read More