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Home > Product > Material & Chemicals > Micro/NanoElectronics > BIS(CYCLOPENTADIENYL)MAGNESIUM

BIS(CYCLOPENTADIENYL)MAGNESIUM | CAS Number: 1284-72-6

Catalog Number
ACM1284726
Product Name
BIS(CYCLOPENTADIENYL)MAGNESIUM
Structure
CAS Number
1284-72-6
Synonyms
Magncsocenc;Magnesium, bis(eta5-2,4-cyclopentadien-1-yl)-;BIS(CYCLOPENTADIENYL)MAGNESIUM;BIS(CYCLOPENTADIENYL)MAGNESIUM(II);DICYCLOPENTADIENYL MAGNESIUM;MAGNESOCENE, SUBLIMED, 97%;Bis(cyclopentadienyl)magnesium(99.9+%-Mg);Bis(cyclopentadienyl)magnesium(99
Molecular Weight
154.49
Molecular Formula
C10H10Mg 10*
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1Magnesocene-Based Electrolytes: A New Class of Electrolytes for Magnesium Batteries.

Schwarz R1, Pejic M1, Fischer P1, Marinaro M1, Jörissen L1, Wachtler M1.

Angew Chem Int Ed Engl. 2016 Nov 21;55(48):14958-14962. doi: 10.1002/anie.201606448. Epub 2016 Oct 28.

Unlike ferrocene, bis(η5 -cyclopentadienyl)magnesium (magnesocene, MgCp2 ) is slightly dissociated in solvents, such as ethers, resulting in electrolyte solutions with low conductivity. MgCp2 /tetrahydrofuran solutions make possible reversible magnesium plating and stripping with low over-potentials for many cycles. The Mg deposits appear with a cauliflower-like morphology. IR and NMR spectroscopy confirm that the electrolyte is stable and not decomposed during prolonged cycling. Read More

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