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Home > Product > Precious Metal Catalyst > Bis(benzonitrile)palladium(II)chloride

Bis(benzonitrile)palladium(II)chloride | CAS Number: 14220-64-5

Catalog Number
ACM14220645
Product Name
Bis(benzonitrile)palladium(II)chloride
Structure
CAS Number
14220-64-5
EC Number
238-085-3
MDL Number
MFCD00013123
IUPAC Name
benzonitrile;dichloropalladium
Synonyms
Bis(benzonitrile)dichloropalladium(II)
Molecular Weight
383.55
Exact Mass
381.92600
Molecular Formula
(C6H5CN)2PdCl2
Boiling Point
191.1ºC at 760 mmHg
Melting Point
131 °C(lit.)
Flash Point
71.7ºC
Purity
Pd ≥27.7%
Appearance
yellow powder
SMILES
C1=CC=C(C=C1)C#N.C1=CC=C(C=C1)C#N.Cl[Pd]Cl
InChIKey
WXNOJTUTEXAZLD-UHFFFAOYSA-L
Safty Description
S23
Hazard Statements
Xn:Harmful;
WGK Germany
3
Stability
Stable at normal temperatures in tightly closed containers under an inert atmosphere.
Packing Group
III
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1Palladium-catalyzed thiocarbonylation of aryl, vinyl, and benzyl bromides.

Burhardt MN1, Ahlburg A, Skrydstrup T.

J Org Chem. 2014 Dec 19;79(24):11830-40. doi: 10.1021/jo5009965. Epub 2014 Jun 17.

A catalytic protocol for synthesis of thioesters from aryl, vinyl, and benzyl bromides as well as benzyl chlorides was developed using only stoichiometric amounts of carbon monoxide, produced from a solid CO precursor inside a two-chamber system. As a catalytic system, the combination of bis(benzonitrile) palladium(II) chloride and Xantphos furnished the highest yields of the desired compounds, along with the weak base, NaOAc, in anisole at 120 °C. Read More

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Tel:1-201-478-8534
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Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA