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Home > Product > Material & Chemicals > Micro/NanoElectronics > Bis(4-tert-butylphenyl)iodonium hexafluorophosphate

Bis(4-tert-butylphenyl)iodonium hexafluorophosphate | CAS Number: 61358-25-6

Catalog Number
ACM61358256
Product Name
Bis(4-tert-butylphenyl)iodonium hexafluorophosphate
Structure
CAS Number
61358-25-6
Synonyms
BIS(4-TERT-BUTYLPHENYL)IODONIUM HEXAFLUOROPHOSPHATE;Iodonium bis[4-(1,1-dimethylethyl)phenyl] Hexafluorophospha;Bis(4-t-butyl phenyl)iodonium hexafluorophosphate
Molecular Weight
538.29
Molecular Formula
C20H26F6IP
Purity
>98.0%(LC)(T)
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1Trialkyl phosphites and diaryliodonium salts as co-initiators in a system for radical-promoted visible-light-induced cationic polymerization.

Nalli TW1, Stanek LG, Molenaar RH, Weidell KL, Meyer JP, Johnson BR, Steckler TT, Wackerly JW, Studler MJ, Vickerman KL, Klankowski SA.

J Org Chem. 2013 Apr 19;78(8):3561-9. doi: 10.1021/jo302830r. Epub 2013 Apr 2.

Trialkyl phosphites ((RO)3P) can act as co-initiators for the diaryliodonium-induced cationic polymerization of cyclohexene oxide (CHO) or THF. A radical initiation step is also required, consistent with the essential role of a radical chain reaction of the phosphite with the iodonium salt to form polymerization-starting aryltrialkoxyphosphonium salts (ArP(+)(OR)3). We used the visible photolysis of phenylazoisobutyronitrile (PAIBN) as the radical initiation step. Read More

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Tel:1-201-478-8534
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