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Home > Product > Material & Chemicals > Micro/NanoElectronics > Bis(2,4,6-trimethylpyridine)iodine(i)hexafluorophosphate

Bis(2,4,6-trimethylpyridine)iodine(i)hexafluorophosphate | CAS Number: 113119-46-3

Catalog Number
ACM113119463
Product Name
Bis(2,4,6-trimethylpyridine)iodine(i)hexafluorophosphate
Structure
CAS Number
113119-46-3
Synonyms
BIS(2,4,6-TRIMETHYLPYRIDINE)IODINE(I) HEXAFLUOROPHOSPHATE;BIS(2,4,6-TRIMETHYLPYRIDINE)IODONIUM HEXAFLUOROPHOSPHATE;BIS(2,4,6-TRIMETHYLPYRIDINE)IODINE(I) HEXAFLUORO PHOSPHATE 99+%;Bis(2,4,6-trimethylpyridine)iodine(I) hexafluorophosphate 97%
Molecular Weight
514.23
Molecular Formula
C16H22F6IN2P
Purity
>98.0%(LC)
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1Diindenopyrenes: Extended 1,6- and 1,8-Pyrenoquinodimethanes with Singlet Diradical Characters.

Hibi D1, Kitabayashi K1, Fujita K1, Takeda T1, Tobe Y1.

J Org Chem. 2016 May 6;81(9):3735-43. doi: 10.1021/acs.joc.6b00389. Epub 2016 Apr 8.

Diindenopyrene 4b and its diastereomer, which are extended homologues of 1,6- and 1,8-pyrenoquinodimethanes fused by indene units, respectively, were synthesized by reaction of 1,4,5,8-tetrakis(mesitylethynyl)naphthalene (7) with bis(2,4,6-trimethylpyridine)iodine(I) hexafluorophosphate via cationic cyclization mechanisms at both centers of reaction. Unexpectedly, reaction of 7 with iodine, a reagent that typically gives products of cationic cyclization, gave cycloheptapentalenoindenophenalene derivative 9b and its diastereomer incorporating an azulene unit at one end of the π framework, via two different modes (radical and cationic) of cyclization at each reaction site. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA