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Home > Product > Metal Organics > Organic Copper > Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(ii)

Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(ii) | CAS Number: 14040-05-2

Catalog Number
ACM14040052
Product Name
Bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(ii)
Structure
CAS Number
14040-05-2
IUPAC Name
copper; 2,2,6,6-tetramethylheptane-3,5-dione
Synonyms
COPPER BIS(DIPIVALOYLMETHANATE);COPPER BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE);COPPER BIS(2,2,6,6-TETRAMETHYLHEPTANE-3,5-DIONE);COPPER(II) BIS(2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE);COPPER II 2,2,6,6-TETRAMETHYL-3,5-HEPTANEDIONATE;CU(TMHD)2;COPPER(II
Molecular Weight
430.08
Exact Mass
431.22200
Molecular Formula
C22H38CuO4
Boiling Point
315ºC
Melting Point
198ºC (dec.)(lit.)
Purity
96%
Appearance
Purple crystalline solid.
InChIKey
LJNKLCWPWAPYME-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
4
Safty Description
S26
Hazard Statements
Xi
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1Photofragmentation pathways and photodeposition of nanoparticles from a gas phase copper-containing precursor.

Rutkowski PX1, Zink JI.

Inorg Chem. 2009 Feb 16;48(4):1655-60. doi: 10.1021/ic802138p.

Pulsed laser excitation of bis(2,2,6,6-tetramethyl-3,5-heptanedionato)copper(II) (Cu(TMHD)(2)) in the gas phase produced neutral gaseous copper atoms and nanoparticulate copper deposits on substrates. Copper atoms were formed by the complete dissociation of the ligands from the metal. Time of flight mass spectrometry and resonance enhanced multiphoton ionization spectroscopy were used to study the details of this reaction and led to the discovery of other gaseous fragments that were produced by incomplete fragmentation of the ligands including monoligated species and coordinated ligand fragments. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA