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Antimony trifluoride | CAS Number: 7783-56-4

Catalog Number
ACM7783564
Product Name
Antimony trifluoride
Structure
CAS Number
7783-56-4
Synonyms
ANTIMONY(III) FLUORIDE;Antimony(Ⅲ)fluoride;ANTIMONY FLUORIDE;ANTIMONY FLUORIDE, TRI;ANTIMONY TRIFLUORIDE;Antimoine fluorure;antimoinefluorure;antimoinefluorure(french)
Molecular Weight
178.76
Molecular Formula
F3Sb
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1Unusual neutral ligand coordination to arsenic and antimony trifluoride.

Levason W1, Light ME, Maheshwari S, Reid G, Zhang W.

Dalton Trans. 2011 May 21;40(19):5291-7. doi: 10.1039/c1dt10113g. Epub 2011 Apr 6.

The preparations and spectroscopic characterisation of the hydrolytically unstable As(III) complexes, [AsF(3)(OPR(3))(2)] (R = Me or Ph) and [AsF(3){Me(2)P(O)CH(2)P(O)Me(2)}] are described and represent the first examples of complexes of AsF(3) with neutral ligands. The crystal structure of [AsF(3){Me(2)P(O)CH(2)P(O)Me(2)}] contains dimers with bridging diphosphine dioxide, but there are also long contacts between the dimers to neighbouring phosphine oxide groups, completing a very distorted six-coordination at arsenic and producing a weakly associated polymer structure. Read More

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA