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Allyl phenyl ether | CAS Number: 1746-13-0

Catalog Number
ACM1746130
Product Name
Allyl phenyl ether
Structure
CAS Number
1746-13-0
Synonyms
(2-propenyloxy)-benzen;(prop-2-enyloxy)-benzene;3-Phenoxypropene;Allyl phenoxylate;Ether, allyl phenyl;ether,allylphenyl;Phenyl 2-propenyl ether;Phenylpropenyl ether
Molecular Weight
134.18
Molecular Formula
C9H10O
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1Iron-catalyzed ortho-allylation of aromatic carboxamides with allyl ethers.

Asako S1, Ilies L, Nakamura E.

J Am Chem Soc. 2013 Nov 27;135(47):17755-7. doi: 10.1021/ja4106368. Epub 2013 Nov 13.

Arenes possessing an N-(quinolin-8-yl)amide directing group are ortho-allylated with allyl phenyl ether in the presence of an iron/diphosphine catalyst and an organometallic base at 50-70 °C. The reaction proceeds via fast iron-catalyzed C-H activation, followed by reaction of the resulting iron intermediate with the allyl ether in γ-selective fashion.

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Email:
Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA