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Allyl butyl ether | CAS Number: 3739-64-8

Catalog Number
ACM3739648
Product Name
Allyl butyl ether
Structure
CAS Number
3739-64-8
EC Number
223-122-8
IUPAC Name
1-prop-2-enoxybutane
Synonyms
3-Butoxy-1-propene;Ether, allyl butyl;BUTYL ALLYL ETHER;ALLYL N-BUTYL ETHER;ALLYL BUTYL ETHER;1-(allyloxy)butane;1-(2-Propenyloxy)butane;1-prop-2-enoxybutane
Molecular Weight
114.19
Exact Mass
114.10400
Molecular Formula
C7H14O
Boiling Point
119.4ºC at 760mmHg
Flash Point
14.4ºC
Density
0.784g/cm3
Purity
96%
SMILES
CCCCOCC=C
InChIKey
IBTLFDCPAJLATQ-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
1
Safty Description
16-26-36
Hazard Statements
F: Flammable;Xi: Irritant;
Packing Group
II
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1Palladium-Catalyzed Anti-Markovnikov Oxidation of Allylic Amides to Protected β-Amino Aldehydes.

Dong JJ1, Harvey EC, Fañanás-Mastral M, Browne WR, Feringa BL.

J Am Chem Soc. 2014 Dec 10;136(49):17302-7. doi: 10.1021/ja510163w. Epub 2014 Dec 1.

A general method for the preparation of N-protected β-amino aldehydes from allylic amines or linear allylic alcohols is described. Here the Pd(II)-catalyzed oxidation of N-protected allylic amines with benzoquinone is achieved in tBuOH under ambient conditions with excellent selectivity toward the anti-Markovnikov aldehyde products and full retention of configuration at the allylic carbon. The method shows a wide substrate scope and is tolerant of a range of protecting groups. Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA