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Allyl acetate | CAS Number: 591-87-7

Catalog Number
ACM591877
Product Name
Allyl acetate
Structure
CAS Number
591-87-7
Synonyms
2-Propenyl acetate;2-Propenyl ester of acetic acid;2-propenylmethanoate;3-acetoxy-1-propene;acetated’allyle;Aceticacid,2-propenylester;aceticacidprop-2-enylester;CH2=C(CH3)OC(=O)CH3
Molecular Weight
100.12
Molecular Formula
C5H8O2
Purity
99%
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1Olefination of Electron-Deficient Alkenes with Allyl Acetate: Stereo- and Regioselective Access to (2Z,4E)-Dienamides.

Li F1, Yu C1, Zhang J1, Zhong G1.

Org Lett. 2016 Sep 16;18(18):4582-5. doi: 10.1021/acs.orglett.6b02229. Epub 2016 Sep 1.

A Ru-catalyzed direct olefination of electron-deficient alkenes with allyl acetate via C-H bond activation is disclosed. By using N,N-disubstituted aminocarbonyl as the directing group, this external oxidant-free protocol resulted in high reaction efficiency and good stereo- and regioselectivities, which opens a novel synthetic passway for access to (Z,E)-butadiene skeletons.

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Email:
Tel:1-201-478-8534
1-516-662-5404
Fax: 1-516-927-0118
Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA