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Triphenylmethylsilane | CAS Number: 791-29-7

Catalog Number
ACM791297
Product Name
Triphenylmethylsilane
Structure
CAS Number
791-29-7
IUPAC Name
methyl(triphenyl)silane
Synonyms
methyl(triphenyl)silane;
Category
Alkylsilane
Molecular Weight
274.43
Exact Mass
274.11800
Molecular Formula
C19H18Si
Boiling Point
352.9ºC at 760 mmHg
Melting Point
69ºC
Flash Point
153.4ºC
Density
1.04 g/cm3
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C1=CC=CC=C1)(C2=CC=CC=C2)C3=CC=CC=C3
InChIKey
GIGVICQLYWGMGW-UHFFFAOYSA-N
Safty Description
S22-S24/25
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1Triplet- vs. singlet-state imposed photochemistry. The role of substituent effects on the photo-Fries and photodissociation reaction of triphenylmethyl silanes.

Zarkadis AK1, Georgakilas V, Perdikomatis GP, Trifonov A, Gurzadyan GG, Skoulika S, Siskos MG.

Photochem Photobiol Sci. 2005 Jun;4(6):469-80. Epub 2005 May 11.

The photochemistry of three structurally very similar triphenylmethylsilanes 1, 2, 3 [p-X-C(6)H(4)-CPh(2)-SiMe(3): X = PhCO, 1; H, ; Ph(OCH(2)CH(2)O)C, 3] is described by means of 248 and 308 nm nanosecond laser flash photolysis (ns-LFP), femtosecond LFP, EPR spectroscopy, emission spectroscopy (fluorescence, phosphorescence), ns-pulse radiolysis (ns-PR), photoproduct analysis studies in MeCN, and X-ray crystallographic analysis of the two key-compounds 1 and 2. Read More

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Email:
Tel:1-201-478-8534
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Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA