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Home > Product > Organic Silicon Compounds > Diphenylmethylsilane

Diphenylmethylsilane | CAS Number: 776-76-1

Catalog Number
ACM776761
Product Name
Diphenylmethylsilane
Structure
CAS Number
776-76-1
EC Number
212-281-9
IUPAC Name
methyl(diphenyl)silicon
Synonyms
Diphenylmethylsilane, Methyldiphenylsilane, Silane, methyldiphenyl-, 261688_ALDRICH, NSC111638, EINECS 212-281-9, Benzene, 1,1-(methylsilylene)bis-, CID6327660, NSC 111638, 776-76-1
Category
Organic hydrogen silane
Molecular Weight
198.34
Exact Mass
198.08600
Molecular Formula
C13H14Si
Boiling Point
93-94ºC1 mm Hg(lit.)
Melting Point
20ºC
Flash Point
>230 °F
Density
0.995 g/mL at 25ºC(lit.)
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C1=CC=CC=C1)C2=CC=CC=C2
InChIKey
OKHRRIGNGQFVEE-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
0
Safty Description
S26-S36
Hazard Statements
Xi
WGK Germany
1
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1Intermolecular antiselective and enantioselective reductive coupling of enones and aromatic aldehydes with chiral Rh(Phebox) catalysts.

Shiomi T1, Adachi T, Ito J, Nishiyama H.

Org Lett. 2009 Feb 19;11(4):1011-4. doi: 10.1021/ol802939u.

The intermolecular reductive coupling reaction of cyclopent-2-enone and aromatic aldehydes was realized by chiral rhodium-(bisoxazolinyl)phenyl catalysts, Rh(Phebox-Ph)(OAc)(2)(H(2)O), with diphenymethylsilane as a hydride donor to give the corresponding beta-hydroxyketones in high anti-selectivity (up to 96%) with high enantioselectivity (up to 93%).

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA