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Allyltrimethylsilane | CAS Number: 762-72-1

Catalog Number
ACM762721
Product Name
Allyltrimethylsilane
Structure
CAS Number
762-72-1
EC Number
212-104-5
IUPAC Name
trimethyl(prop-2-enyl)silane
Synonyms
Allyltrimethylsilane, Silane, allyltrimethyl-, Silane, trimethyl-2-propenyl-, allyl(trimethyl)silane, 3-(Trimethylsilyl)propene, ALLYL TRIMETHYLSILANE, CCRIS 2649, 208264_ALDRICH, EINECS 212-104-5, CID69808, LS-188195, TL8005210, InChI=1/C6H14Si/c1-5-6-7(2,3)4/h5H,1,6H2,2-4H, 762-72-1
Category
Alkenyl silane
Molecular Weight
114.26
Molecular Formula
C6H14Si
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)(C)CC=C
InChIKey
HYWCXWRMUZYRPH-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
0
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1Gold(i)-catalyzed C-glycosylation of glycosyl ortho-alkynylbenzoates: the role of the moisture sequestered by molecular sieves.

Chen X1, Wang Q1, Yu B1.

Chem Commun (Camb). 2016 Oct 6;52(82):12183-12186.

C-Glycosylation of glycosyl ortho-hexynylbenzoates with allyltrimethylsilane or silyl enol ethers could proceed smoothly under the catalysis of Ph3PAuNTf2 to provide the corresponding C-glycosides in high yields and stereoselectivity, wherein the moisture sequestered by the molecular sieves was disclosed to play a critical role in the gold(i)-catalytic cycle.

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Email:
Tel:1-201-478-8534
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Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA