Ishikawa H1, Kawasaki T, Inomata R.
J Phys Chem A. 2015 Jan 29;119(4):601-9. doi: 10.1021/jp5097508. Epub 2015 Jan 20.Spectroscopic and theoretical investigations have been carried out for neutral phenol-triethylsilane clusters to reveal an intrinsic nature of the Si-H···H-O type dihydrogen bond. On the basis of the laser-induced fluorescence and infrared spectra, four isomers are identified. Three of them have a structure in which the dihydrogen bond and the dispersion interaction are competing in the stabilization of the cluster. Read More