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Home > Product > Organic Building Blocks > Organic Silicon Compounds > Other Organosilicon > 1,1,3,3-Tetraphenyl-1,3-dimethyldisilazane

1,1,3,3-Tetraphenyl-1,3-dimethyldisilazane | CAS Number: 7453-26-1

Catalog Number
ACM7453261
Product Name
1,1,3,3-Tetraphenyl-1,3-dimethyldisilazane
Structure
CAS Number
7453-26-1
IUPAC Name
1,3-DIMETHYL-1,1,3,3-TETRAPHENYLDISILAZANE
Synonyms
1-methyl-N-(methyldiphenylsilyl)-1,1-diphenylsilylamine; Di(diphenylmethylsilyl)amin; TPDMDS; 1,3-Dimethyl-1,1,3,3-tetraphenylpropanedisilazane; Bis(methyldiphenylsilyl)amine; N,N-Bis-(diphenylmethyl-silyl)-amin; 1,1,3,3-TETRAPHENYLDIMETHYLDISILAZANE; 1,1,3,3-Tetraphenyl-1,3-dimethylpropanedisilazane; 1,1,3,3-TETRAPHENYL-1,3-DIMETHYLDISILAZANE; 1,3-Dimethyl-1,1,3,3-tetraphenyl-disilazan;
Category
Organic amino silane
Molecular Weight
409.67
Exact Mass
409.16800
Molecular Formula
C26H27NSi2
Boiling Point
210-220ºC (0.5 mmHg)
Melting Point
87-89ºC(lit.)
Flash Point
>110ºC
Density
1.07g/cm3
Purity
95%+
Appearance
Transparent liquid
Safty Description
S26-S36
Hazard Statements
Xi
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1A heterobimetallic superoxide complex formed through O2 activation between chromium(II) and a lithium cation.

Schax F1, Suhr S, Bill E, Braun B, Herwig C, Limberg C.

Angew Chem Int Ed Engl. 2015 Jan 19;54(4):1352-6. doi: 10.1002/anie.201409294. Epub 2014 Dec 4.

The reaction of 1,1,3,3-tetraphenyl-1,3-disiloxandiol (LH2) with n-butyllithium and CrCl2 results in a mononuclear chromium(II) complex (1) that further reacts with O2 at low temperatures to yield a mononuclear chromium(III) superoxide complex [L2CrO2(THF)][Li2(THF)3] (2). The crystal structure revealed that the chromium superoxido entity is stabilized by the coordination to an adjacent lithium cation. Read More

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