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Allyldimethylsilane | CAS Number: 3937-30-2

Catalog Number
ACM3937302
Product Name
Allyldimethylsilane
Structure
CAS Number
3937-30-2
IUPAC Name
dimethyl(prop-2-enyl)silicon
Synonyms
HMe2allylSi; dimethyl-2-propenyl-Silane; allyl-dimethyl-silane; dimethyl-2-propenyl-silan; Silane,dimethyl-2-propenyl; Allyl-dimethyl-silan; allyltrimrthylsilane; HSiMe2CH2CH=CH2;
Category
Organic hydrogen silane
Molecular Weight
100.23
Exact Mass
100.07100
Molecular Formula
C5H12Si
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)CC=C
InChIKey
ZBMGMUODZNQAQI-UHFFFAOYSA-N
Safty Description
16-26-36
Hazard Statements
F: Flammable;Xi: Irritant;
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1Alpha,beta-unsaturated beta-silyl imide substrates for catalytic, enantioselective conjugate additions: a total synthesis of (+)-lactacystin and the discovery of a new proteasome inhibitor.

Balskus EP1, Jacobsen EN.

J Am Chem Soc. 2006 May 31;128(21):6810-2.

Chiral (salen)Al mu-oxo dimer 1 catalyzes the highly enantioselective conjugate addition of carbon-centered nucleophiles to alpha,beta-unsaturated silyl imides. Allyldimethylsilane-substituted imide 4 was identified as an optimal substrate, undergoing addition reactions with a variety of nitrile nucleophiles in high yield and enantiomeric excess. The silicon-containing products are synthetically useful chiral building blocks, as demonstrated by their application to an enantioselective total synthesis of the potent proteasome inhibitor (+)-lactacystin (2). Read More

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Tel:1-201-478-8534
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Address: Suite 212, Waverly Plaza, 755 Waverly Avenue, Holtsville, NY 11742, USA