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Home > Product > Organic Building Blocks > Organic Silicon Compounds > Other Organosilicon > (2-Bromophenylethynyl)trimethylsilane

(2-Bromophenylethynyl)trimethylsilane | CAS Number: 38274-16-7

Catalog Number
ACM38274167
Product Name
(2-Bromophenylethynyl)trimethylsilane
Structure
CAS Number
38274-16-7
IUPAC Name
2-(2-bromophenyl)ethynyl-trimethylsilane
Synonyms
o-(2-trimethylsilylethynyl)bromomobenzene; 1-(trimethylsilyl-ethynyl)-2-bromo-benzene; 2-bromo-1-[2-(trimethylsilyl)ethynyl]benzene; 1-bromo-2-(trimethylsilylethynyl)benzene; ((2-Bromophenyl)ethynyl)trimethylsilane; 1-bromo-2-[2-(trimethylsilyl)ethynyl]benzene;
Category
Alkynyl silane
Molecular Weight
253.21
Exact Mass
251.99700
Molecular Formula
C11H13BrSi
Boiling Point
60-80ºC2 mm Hg(lit.)
Flash Point
>230 °F
Density
1.19 g/mL at 25ºC(lit.)
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)(C)C#CC1=CC=CC=C1Br
InChIKey
FABNGXSCLHXUOH-UHFFFAOYSA-N
WGK Germany
3
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1Synthesis and properties of a twistophane ion sensor: a new conjugated macrocyclic ligand for the spectroscopic detection of metal ions.

Baxter PN1.

J Org Chem. 2001 Jun 15;66(12):4170-9.

The synthesis of a structurally new type of conjugated macrocyclic ligand (1) is reported that comprises a dehydroannulene framework incorporating two 2,2'-bipyridine units. Modeling studies showed the ligand to possess an unusual chirally twisted and relatively rigid architecture capable of binding metal ions in an enforced tetrahedral coordination geometry. The macrocycle was prepared in seven steps from (2-bromophenylethynyl)-trimethylsilane (2) and characterized by spectroscopic techniques. Read More

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Tel:1-201-478-8534
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Fax: 1-516-927-0118
Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA