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p-Tolyltrimethylsilane | CAS Number: 3728-43-6

Catalog Number
ACM3728436
Product Name
p-Tolyltrimethylsilane
Structure
CAS Number
3728-43-6
IUPAC Name
trimethyl-(4-methylphenyl)silane
Synonyms
Silane, p-tolyl-trimethyl-,, MolPort-006-709-277, NSC170018, CID298149, 3728-43-6
Category
Alkylsilane
Molecular Weight
164.32
Exact Mass
164.10200
Molecular Formula
C10H16Si
Boiling Point
190ºC (33 torr)
Flash Point
51.6ºC
Density
0.86
Purity
95%+
Appearance
Transparent liquid
InChIKey
QGHURGPPCGMAMZ-UHFFFAOYSA-N
H-Bond Donor
0
H-Bond Acceptor
0
Safty Description
37/39-26-16
Hazard Statements
Xi: Irritant;
Packing Group
III
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1A highly enantioselective Hg(ii)-catalyzed Sakurai-Hosomi reaction of isatins with allyltrimethylsilanes.

Cao ZY1, Jiang JS, Zhou J.

Org Biomol Chem. 2016 Jun 28;14(24):5500-4. doi: 10.1039/c5ob02582f. Epub 2016 Jan 6.

A chiral complex derived from (S)-difluorophos and Hg(OTf)2 is identified as a powerful catalyst for the Sakurai-Hosomi reaction of isatins with allyltrimethylsilane, allowing the facile synthesis of valuable building blocks 3-allyl-3-hydroxyoxindoles in up to 97% ee, with only 0.5-1.0 mol% of catalyst loading.

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Tel:1-201-478-8534
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Address: 2200 Smithtown Avenue, Room 1 Ronkonkoma, NY 11779-7329 USA