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Home > Product > Organic Silicon Compounds > Methyl trimethylsilylacetate

Methyl trimethylsilylacetate | CAS Number: 2916-76-9

Catalog Number
ACM2916769
Product Name
Methyl trimethylsilylacetate
Structure
CAS Number
2916-76-9
EC Number
220-845-0
IUPAC Name
methyl2-trimethylsilylacetate
Synonyms
Methyl (trimethylsilyl)acetate; (Me)3SiCH2CO2Me; methy C-(trimethylsilyl)acetate; Me3SiCH2CO2CH3; (carbomethoxymethyl)trimethylsilane; methyl 2-(trimethylsilyl)acetate; TMSCH2CO2Me; Methyl(trimethylsilyl)acetate; JIHUZDFFYVRXKP-UHFFFAOYSA;
Category
Silicon hydrocarbyl carboxylic acids compounds
Molecular Weight
146.26
Exact Mass
146.07600
Molecular Formula
C6H14O2Si
Boiling Point
140.8ºC at 760mmHg
Flash Point
23.1ºC
Density
0.876g/cm3
Purity
95%+
Appearance
Transparent liquid
SMILES
COC(=O)C[Si](C)(C)C
InChIKey
JIHUZDFFYVRXKP-UHFFFAOYSA-N
Safty Description
16-26-36
Hazard Statements
F: Flammable;Xi: Irritant;
Packing Group
II
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1A highly stereoselective synthesis of 11Z-retinal using tricarbonyliron complex.

Wada A1, Fujioka N, Tanaka Y, Ito M.

J Org Chem. 2000 Apr 21;65(8):2438-43.

A stereoselective synthesis of 11Z-retinal 2, which is the chromophore of visual pigment (rhodopsin), was accomplished from the beta-ionylideneacetaldehyde-tricarbonyliron complex 3. The Peterson reaction of 3 using ethyl trimethylsilylacetate smoothly proceeded to afford predominantly the Z-ester 6. Transformation of the Z-ester 6 to the methyl ketone 19, followed by the Emmons-Horner reaction of 19 with C2-cyanophosphonate, produced ethyl 11Z, 13E-retinonitrile-tricarbonyliron complex 21 as the only product. Read More

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Tel:1-201-478-8534
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