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Home > Product > Organic Silicon Compounds > Siloxanes > N,o-Bis(trimethylsilyl)hydroxylamine

N,o-Bis(trimethylsilyl)hydroxylamine | CAS Number: 22737-37-7

Catalog Number
ACM22737377
Product Name
N,o-Bis(trimethylsilyl)hydroxylamine
Structure
CAS Number
22737-37-7
EC Number
245-188-7
IUPAC Name
[dimethyl-(trimethylsilyloxyamino)silyl]methane
Synonyms
N,O-Bis(trimethylsilyl)hydroxylamine; EINECS 245-188-7; Me3SiNHOSiMe3;
Category
Ammonia hydroxyl silane
Molecular Weight
177.39
Exact Mass
177.10100
Molecular Formula
C6H19NOSi2
Boiling Point
139.8ºC at 760 mmHg 78-80ºC100 mm Hg(lit.)
Flash Point
38.3ºC
Density
0.828 g/cm3
Purity
95%+
Appearance
Transparent liquid
SMILES
C[Si](C)(C)NO[Si](C)(C)C
InChIKey
ZAEUMMRLGAMWKE-UHFFFAOYSA-N
Safty Description
S26
Hazard Statements
Xi: Irritant;
WGK Germany
3
Packing Group
III
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1Simultaneous GC-MS/MS measurement of malondialdehyde and 4-hydroxy-2-nonenal in human plasma: Effects of long-term L-arginine administration.

Tsikas D1, Rothmann S2, Schneider JY2, Gutzki FM2, Beckmann B2, Frölich JC2.

Anal Biochem. 2016 Aug 13. pii: S0003-2697(16)30237-8. doi: 10.1016/j.ab.2016.08.009. [Epub ahead of print]

Here, we report the simultaneous derivatization and quantification of malondialdehyde (MDA) and 4-hydroxy-2-nonenal (HNE) in human plasma by GC-MS/MS using [1,3-2H2]-MDA (d2-MDA) and [9,9,9-2H3]-HNE (d3-HNE) as the internal standards, respectively. MDA, d2-MDA, HNE and d3-HNE were converted to their pentafluorobenzyl oximes (PFBOX) by pentafluorobenzyl hydroxylamine. Subsequently, the hydroxyl groups of the PFBOX of HNE and d3-HNE were trimethylsilylated with N,O-bis(trimethylsilyl)trifluoroacetamide/1% trimethylchlorosilane. Read More

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